Search results for "ISM: molecules"
showing 5 items of 5 documents
The hyperfine structure in the rotational spectrum of CF+
2012
Context. CF+ has recently been detected in the Horsehead and Orion Bar photo-dissociation regions. The J=1-0 line in the Horsehead is double-peaked in contrast to other millimeter lines. The origin of this double-peak profile may be kinematic or spectroscopic. Aims. We investigate the effect of hyperfine interactions due to the fluorine nucleus in CF+ on the rotational transitions. Methods. We compute the fluorine spin rotation constant of CF+ using high-level quantum chemical methods and determine the relative positions and intensities of each hyperfine component. This information is used to fit the theoretical hyperfine components to the observed CF+ line profiles, thereby employing the h…
Zeeman effect in sulfur monoxide: A tool to probe magnetic fields in star forming regions
2017
[Context] Magnetic fields play a fundamental role in star formation processes and the best method to evaluate their intensity is to measure the Zeeman effect of atomic and molecular lines. However, a direct measurement of the Zeeman spectral pattern from interstellar molecular species is challenging due to the high sensitivity and high spectral resolution required. So far, the Zeeman effect has been detected unambiguously in star forming regions for very few non-masing species, such as OH and CN.
SOFT X-RAY IRRADIATION OF PURE CARBON MONOXIDE INTERSTELLAR ICE ANALOGUES
2012
There is an increasing evidence for the existence of large organic molecules in the interstellar and circumstellar medium. Very few among such species are readily formed in conventional gas-phase chemistry under typical conditions of interstellar clouds. Attention has therefore focused on interstellar ices as a potential source of these relatively complex species. Laboratory experiments show that irradiation of interstellar ice analogues by fast particles or ultraviolet radiation can induce significant chemical complexity. However, stars are sources of intense X-rays at almost every stage of their formation and evolution. Such radiation may thus provide chemical changes in regions where ult…
Soft X-Ray Irradiation of Methanol Ice: Implication for H2CO Formation in Interstellar Regions
2010
We performed 0.3 keV soft X-ray irradiation of a methanol ice at 8 K under ultra-high vacuum conditions. To the best of our knowledge, this is the first time that soft X-rays are used to study photolysis of ice analogs. Despite the low irradiation dose of 10{sup -6} photons molecule{sup -1}, the formation of formaldehyde has been observed. The results of our experiments suggest that X-rays may be a promising candidate to the formation of complex molecules in regions where UV radiation is severely inhibited.
Laboratory measurements and astronomical search for the HSO radical
2016
[Context] Despite the fact that many sulfur-bearing molecules, ranging from simple diatomic species up to astronomical complex molecules, have been detected in the interstellar medium, the sulfur chemistry in space is largely unknown and a depletion in the abundance of S-containing species has been observed in the cold, dense interstellar medium. The chemical form of the missing sulfur has yet to be identified.